Authors: I.Z. Ismagilov, E.V. Matus, V.V. Kuznetsov, M.A. Kerzhentsev, S.A. Yashnik, N. Mota, R.M. Navarro, J.L.G. Fierro, T.N. Teryaeva, Z.R. Ismagilov
Title of the article: Autothermal reforming of methane: Part 2. Effect of support composition on the activity of bimetallic NiPd catalyst
Year: 2014, Issue: 5, Pages: 91-95
Branch of knowledge: Chemical technology
Index UDK: 544.478.1:661.961.62
DOI: -
Abstract: To optimize the catalyst formula for ATP of CH4 the catalytic activity of NiPd/Ce0.5Zr0.5O2/Al2O3 и NiPd/La2O3/Ce0.5Zr0.5O2/Al2O3 samples was studied at variation of Ce0.5Zr0.5O2 (10-30 wt.%) and La2O3 (5-20 wt.%) content in the support. The optimal catalyst composition was established. NiPd/20La2O3/10Ce0.5Zr0.5O2/Al2O3 catalyst was characterized by stable activity with time on stream and provides an H2 yield of 65% at conversion of CH4 of 90-100% and at reaction temperature of 850oC.
Key words: methane autothermal reforming bimetallic catalysts
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