Authors: N.G. Malyuta, N.N. Churilova, N.M. Kim, A.V. Sukhoverskaya

Title of the article: The study of physical methods ability intermediates in the synthesis of oxime 3-phenyl-5,5-pentamethylen-4-isoxazolone for complexation

Year: 2015, Issue: 6, Pages: 117-124

Branch of knowledge: Chemical technology

Index UDK: 547.288.4

DOI: -

Abstract: The urgency of the discussed issue: Heterocyclic compounds, their derivatives and complex compounds based on them have optical and electrochemical properties and biological activity than attract the attention of researchers. The main aim of the study: To study the ability to interact intermediates formed in the synthesis of 3-phenyl-5,5-pentamethylene-4-nitroizoksazolina with certain metal cations in alcoholic solutions physical methods. The methods used in the study: IR spectroscopy and spectrophotometry. The results: The ability to interact intermediates formed in the synthesis of 3-phenyl-5,5-pentamethylene-4-nitroizoksazolina with some metal cations (Li+; Na+; Rb+; Mg2 +; Al3+; Cu2+; Sm3+; Co2+) in alcoholic solutions . Reactivity (the ability to form complexes with metal ions) intermediate and target products depend on the electronic state of the fragment C-N-O-.

Key words: oximes isoxazoles isoxazolines ligands complexes IR spectra spectrophotometry

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